نتایج جستجو برای: kritchenko condensation
تعداد نتایج: 32344 فیلتر نتایج به سال:
synthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6h-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7h)-oneabstractnew 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6h-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7h)-one (2a) was synthesized in good yield by the petrenko–kritchenko reaction of 2, 2'-((3-hydroxyp...
Synthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-oneABSTRACTNew 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one (2a) was synthesized in good yield by the Petrenko–Kritchenko reaction of 2, 2'-((3-hydroxyp...
The title compound, C24H29NO4, is the product of a Petrenko-Kritchenko condensation of 1,5-bis-(2-formyl-phen-oxy)-3-oxa-pentane, pentan-3-one and methyl-ammonium acetate in ethanol. The mol-ecule has mirror symmetry. The aza-14-crown-3 ether ring adopts a bowl conformation stabilized by a weak intra-molecular C-H⋯O hydrogen bond. The conformation of the C-O-C-C-O-C-C-O-C polyether chain is t-g...
The title compound, C(25)H(28)N(2)O(5), is a product of the Petrenko-Kritchenko condensation of N-acetyl-piperidone with 1,5-bis-(2-formyl-phen-oxy)-3-oxapentane and ammonium acetate. The mol-ecule comprises a fused penta-cyclic system containing an aza-14-crown-3-ether macrocycle, two piperidone and two benzene rings. The aza-14-crown-3-ether ring adopts a bowl conformation. The dihedral angle...
The title compound, C26H32N2O4(M)·C2H4O2, (I), is the product of the Petrenko-Kritchenko condensation of N-propyl-piperidinone with 1,5-bis-(2-formyl-phen-oxy)-3-oxa-pentane and ammonium acetate. In M, the aza-14-crown-3-ether ring adopts a bowl conformation, with the configuration of the C-O-C-C -O-C-C-O-C polyether chain being t-g ((-))-t-t-g ((+))-t (t = trans, 180°; g = gauche, ±60°). The d...
A Gelfand-Cetlin polytope is a convex polytope obtained as an image of certain completely integrable system on a partial flag variety. In this paper, we give an equivalent description of the face structure of a GC-polytope in terms of so called the face structure of a ladder diagram. Using our description, we obtain a partial differential equation whose solution is the exponential generating fu...
introduction: the purpose of this study was to evaluate the sealing ability of 3 obturation techniques in oval-shaped canals by bacterial leakage assessment. methods: sixty mandibular incisors with oval canals were selected after providing buccolingual and mesiodistal radiographs. the teeth were sectioned at a 10 mm distance from the apex. after instrumentation, the teeth were divided into 3 gr...
Within the Phenacoccinae (Hemiptera: Coccoidea: Pseudococcidae), there are four nominal genera that include species with clusters or groups of multilocular disc pores and/or oral collar tubular ducts of more than one size, namely Peliococcus Borchsenius (= Spinococcus Borchsenius and Eupeliococcus Săvescu), Peliococcopsis Borchsenius, Erimococcus Ezzat, and Seyneria Goux. This study analysed mo...
We introduce two generalized condensation principles: Local Club Condensation and Stationary Condensation. We show that while Strong Condensation (a generalized Condensation principle introduced by Hugh Woodin in [19]) is inconsistent with an ω1-Erdős cardinal, Stationary Condensation and Local Club Condensation (which should be thought of as weakenings of Strong Condensation) are both consiste...
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